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Photoinduced electron transfer across an organic molecular wall: octa acid encapsulated ESIPT dyes as electron donors
Fabiano S Santos1, Elamparuthi Ramasamy, V Ramamurthy
1Department of Chemistry, University of Miami, Coral Gables, Florida 33124, USA.
Abstract:
Efficient photoinduced electron transfer from proton transfer dyes encapsulated within water soluble supramolecular host octa acid to electron acceptors present outside the capsule was observed in aqueous solution. 4,4′-Dimethylviologen dichloride was found to be the best acceptor compared to N-methylpyridinium iodide, most likely due to its better binding with the exterior of the host octa acid walls [corrected].
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