Atomic-scale observation of pressure-dependent reduction dynamics of W₁₈O₄₉ nanowires using environmental TEM

The real-time observation of structural evolution of materials can provide critical information for understanding their reduction mechanisms under different environments. Herein, we report the atomic-scale observation of the reduction dynamics of W₁₈O₄₉ nanowires (NWs) using environmental transmission electron microscopy. Intriguingly, the reduction pathway is found to be affected by oxygen pressure. Under high oxygen pressure (∼0.095 Pa), a W₁₈O₄₉ NW epitaxially transforms into a WO₂ NW via mass transport across the interface between (010)_W and (101)_WO. While under low oxygen pressure (∼0.0004 Pa), the transformation follows the sequence of W₁₈O₄₉(NW) → WO₂(NW) → β-W(nanoparticles), which is identified as a new reduction pathway. These findings reveal the pressure-dependent reduction and a new transformation pathway, and extend our current understanding of the reduction dynamics of metal oxides.