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Cation-Driven Self-Assembly of a Gold(I)-Based Metallo-Tweezer
Susana Ibáñez1, Macarena Poyatos1, Eduardo Peris1
1Institute of Advanced Materials (INAM), Universitat Jaume I, Av. Vicente Sos Baynat s/n, 12071, Castellón, Spain.
Angewandte Chemie (International Ed. in English)
|June 20, 2017
Abstract:
A combination of self-complementary π-π-stacking interactions and metallophilic interactions triggered the self-assembly of a new digold(I) metallo-tweezer in the presence of several types of M+ ions. Titrations by fluorescence spectroscopy enabled the determination of the association constants of the resulting inclusion duplex complexes.

