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Updated: Feb 28, 2026

Biofunctionalization of Magnetic Nanomaterials
Published on: July 16, 2020
Impact of Postsynthetic Modification on the Electrical and Magnetic Properties of Materials
K S Asha1, Niyaz Ahmed2, Ramesh Nath2
1School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram , Thiruvananthapuram, Kerala 695016, India.
Abstract:
Postsynthetic modification is a promising tool for introducing multifunctional properties in metal-organic frameworks (MOFs). The effects of postsynthetic metal addition/exchange in a barium-based MOF have been well examined toward their magnetic and electrical properties. The rattling motion of the extraframework organic cation is responsible for the ferroelectric behavior. The strong magnetic frustration in Tb@1 is found to arise from the nearly triangular arrangement of Tb3+ ions in its secondary building unit along the chain direction.
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