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Updated: Feb 27, 2026

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
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Syntheses, Structures, and Solution Studies of Multicomponent Macrocycles and Cages Based on Versatile Ligands

Ying-Ying Zhang1,2, Wen-Xi Gao1, Yue-Jian Lin1

  • 1Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Fudan University, Shanghai, 200433, P. R. China.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|June 23, 2017
PubMed
Summary

New multinuclear rhodium macrocycles and cages were synthesized using hydroxamate ligands. Researchers observed varying nuclearities and structures depending on ligand size and reaction conditions, yielding diverse metal-organic frameworks.

Keywords:
chelatesheterometallic cagesheterometallic macrocyclesself-assemblytransition metals

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