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Heterocorrole Conformations: Little Saddling, Much Ruffling

Jörn Rösner1, Birte Cordes1, Stefanie Bahnmüller1

  • 1Institute for Inorganic and Analytical Chemistry, TU Braunschweig, Hagenring 30, 38106, Braunschweig, Germany.

Angewandte Chemie (International Ed. in English)
|June 24, 2017
PubMed
Summary

This study investigated metal complexes of heterocorroles, focusing on how the macrocycle cavity size adapts to different metal ions. Researchers found that corrole macrocycles can deform through in-plane bond lengthening and out-of-plane ruffling to accommodate metal ions.

Keywords:
X-ray crystallographyconformation analysiscoordination compoundsheterocorrolesporphyrinoids

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