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Updated: Feb 27, 2026
Synthetic Methodology for Asymmetric Ferrocene Derived Bio-conjugate Systems via Solid Phase Resin-based Methodology
Published on: March 12, 2015
A chelating bis(aminophenol) ligand bridged by a 1,1'-ferrocene-bis(para-phenylene) linker
Daniel D Swanson1, Kyle M Conner, Seth N Brown
1Department of Chemistry and Biochemistry, University of Notre Dame, 251 Nieuwland Science Hall, Notre Dame, IN 46556-5670, USA. Seth.N.Brown.114@nd.edu.
Abstract:
1,1'-Bis(4-(2-hydroxy-3,5-di-tert-butylphenyl)aminophenyl)ferrocene (pFlipH4) is prepared in three steps from commercially available 1,1'-ferrocenediboronic acid or its pinacol ester. The suitability of the ligand to bind as a tetradentate ligand in a cis, planar fashion has been confirmed by formation of a square planar palladium bis-iminosemiquinone (pFlip)Pd. The linker unit appears to be structurally similar to 1,1'-ferrocenediyl, but the electronic interaction of the ferrocene with the aminophenols is minimal.
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