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Structural Studies of Macromolecules in Solution using Small Angle X-Ray Scattering
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Challenges and Perspectives in the Macromolecular Flatland.

Marco Servalli1

  • 1Laboratory of Polymer Chemistry Department of Materials ETH Zurich, CH-8093 Zurich;,

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|July 1, 2017
PubMed
Summary

Two-dimensional polymers (2DPs) are novel, planar macromolecules with potential applications. This review covers their synthesis, characterization challenges, and uses in areas like gas separation membranes.

Area of Science:

  • Polymer Chemistry
  • Materials Science
  • Nanotechnology

Background:

  • Two-dimensional polymers (2DPs), planar macromolecules resembling monolayer covalent sheets, have emerged as a significant development in polymer chemistry.
  • Since the first synthesis in 2012, the field has rapidly advanced, exploring the unique properties and potential of these materials.

Purpose of the Study:

  • To review the progress in 2DP research five years after their initial synthesis.
  • To discuss synthetic methodologies, structural characterization challenges, and potential applications of 2DPs.

Main Methods:

  • The review synthesizes information from various studies on 2DP synthesis.
  • It highlights key examples of synthesized 2DPs and discusses the analytical techniques used for their characterization.

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  • Potential applications are explored based on the properties of these 2D materials.

    • Main Results:

    • Several synthetic approaches for creating 2DPs have been developed, yielding crystalline monolayer covalent sheets.
    • Structural characterization remains a significant challenge due to the unique nature of these macromolecules.
    • Identified potential applications include gas separation membranes, rewritable molecular paper, and components for miniaturized optical devices.

    Conclusions:

    • 2DPs represent a fascinating new class of materials with significant theoretical and practical implications.
    • Continued research into synthesis and characterization is crucial for unlocking their full potential.
    • The diverse applications suggest a promising future for 2DPs in advanced material technologies.