Intricate kinetics: in situ FTIR-spectroscopy discloses a phase change during ionic liquid synthesis
1Institut für Technische Chemie und Makromolekulare, Chemie (ITMC), RWTH Aachen University, Worringerweg 1, 52074 Aachen, Germany. ohligschlaeger@itmc.rwth-aachen.de liauw@itmc.rwth-aachen.de.
Physical Chemistry Chemical Physics : PCCP
|July 1, 2017
Abstract:
The kinetics of the methylation of triethylamine (NEt3) with dimethyl carbonate (DMC) in methanol have been investigated by means of in situ ATR-IR-spectroscopy. The data show an autocatalytic influence of the ionic product on reaction kinetics. A bend in the reaction rate progress indicates a sudden change from solvated ions to a microstructured biphasic system, which is reflected in the dependence of the reaction rate constant on the product concentration and the Hildebrand parameter.


