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![The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
The Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2 F5 )3 ]- -Synthesis and Reactivity
Markus Wiesemann1, Johannes Klösener1, Mark Niemann1
1Centrum für Molekulare Materialien, Fakultät für Chemie, Universität Bielefeld, Universitätsstraße 25, 33615, Bielefeld, Germany.
Abstract:
Syntheses of salts containing the tris(pentafluoroethyl)stannate(II) ion, [Sn(C2 F5 )3 ]- , were achieved through deprotonation of the corresponding stannane, HSn(C2 F5 )3 , as well as by direct pentafluoroethylation of SnCl2 with LiC2 F5 . The electron-withdrawing substituents have substantial influence on the stability and reactivity of the anion as documented by its treatment with main group halides. Alkyl halides (R-X) underwent nucleophilic substitutions to afford RSn(C2 F5 )3 , whereas Si, Ge, Sn, P halides gave rise to oxidation processes yielding hypervalent [SnX2 (C2 F5 )3 ]- salts (X=Cl, Br, I). Moreover the unsymmetrical distannane, nBu3 SnSn(C2 F5 )3 , was disclosed as an alternative precursor for the Sn(C2 F5 )3 moiety. Although neither the solid state structure nor its spectra in alkane solution reveal unexpected peculiarities, unusual dissociation of the compound in coordinating solvents into [nBu3 Sn(D)n ]+ and [Sn(C2 F5 )3 ]- ions was observed.
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