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Updated: Feb 27, 2026

Characterization and Application of Passive Samplers for Monitoring of Pesticides in Water
Published on: August 3, 2016
Predictive quality of 26 pesticide risk indicators and one flow model: A multisite assessment for water contamination
Frédéric Pierlot1, Jonathan Marks-Perreau2, Benoît Réal2
1LAE, Université de Lorraine, INRA, 54500, Vandoeuvre, France; Chambre Régionale d'Agriculture Grand Est, Pôle Recherche Développement et Innovations, France.
Abstract:
Stakeholders need operational tools to assess crop protection strategies in regard to environmental impact. The need to assess and report on the impacts of pesticide use on the environment has led to the development of numerous indicators. However, only a few studies have addressed the predictive quality of these indicators. This is mainly due to the limited number of datasets adapted to the comparison of indicator outputs with pesticide measurement. To our knowledge, evaluation of the predictive quality of pesticide indicators in comparison to the quality of water as presented in this article is unprecedented in terms of the number of tested indicators (26 indicators and the MACRO model) and in terms of the size of datasets used (data collected for 4 transfer pathways, 20 active ingredients (a.i.) for a total of 1040 comparison points). Results obtained on a.i. measurements were compared to the indicator outputs, measured by: (i) correlation tests to identify linear relationship, (ii) probability tests comparing measurements with indicator outputs, both classified in 5 classes, and assessing the probability i.e. the percentage of correct estimation and overestimation (iii) by ROC tests estimating the predictive ability against a given threshold. Results showed that the correlation between indicator outputs and the observed transfers are low (r<0.58). Overall, more complex indicators taking into account the soil, the climatic and the environmental aspects yielded comparatively better results. The numerical simulation model MACRO showed much better results than those for indicators. These results will be used to help stakeholders to appropriately select their indicators, and will provide them with advice for possible use and limits in the interpretation of indicator outputs.
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