Scrolling up graphene oxide nanosheets assisted by self-assembled monolayers of alkanethiols

We report a simple and novel method for the fabrication of high-quality nanoscrolls of graphene oxide (GO) and graphene oxide decorated with silver nanoparticles (GO-Ag) on a gold substrate through a scrolling process assisted by the self-assembly of alkanethiol monolayers. The yield and rate of the scrolling process were highly dependent on the lengths of the alkanethiol molecules, and could be well described by power law functions. Importantly, compared to nanosheets, nanoscrolls of GO and GO-Ag showed superior performance in humidity sensing due to their unique scrolled structures.