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Decompression-Driven Superconductivity Enhancement in In2 Se3.

Feng Ke1, Haini Dong1,2, Yabin Chen3

  • 1Center for High Pressure Science and Technology Advanced Research, Shanghai, 201203, China.

Advanced Materials (Deerfield Beach, Fla.)
|July 11, 2017
PubMed
Summary
This summary is machine-generated.

Superconductivity in indium selenide (In2Se3) was unexpectedly enhanced upon decompression, reaching a critical temperature of 8.2 K. This discovery suggests maintaining superconductivity at lower pressures.

Keywords:
layered materialsphonon-modulated superconductivitypressurestructural transitionsuperconductivity enhancement

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Superconductivity Research

Background:

  • Indium selenide (In2Se3) is a layered chalcogenide material.
  • Superconductivity is a phenomenon observed in certain materials at low temperatures and high pressures.
  • Understanding pressure-induced phase transitions is crucial for discovering new superconducting materials.

Purpose of the Study:

  • To investigate the superconducting properties of indium selenide (In2Se3) under varying pressure conditions.
  • To explore the effect of pressure-induced structural transitions on superconductivity.
  • To determine if superconductivity can be enhanced or maintained during pressure release.

Main Methods:

  • High-pressure experiments were conducted on In2Se3.
  • Superconductivity was measured by monitoring critical temperature (Tc) as a function of pressure.
  • Structural transitions were analyzed in conjunction with superconducting properties during compression and decompression.

Main Results:

  • Superconductivity onset in In2Se3 was observed at 41.3 GPa with a Tc of 3.7 K, peaking at 47.1 GPa.
  • A significant enhancement of superconductivity was observed during decompression, with Tc reaching 8.2 K at 10.7 GPa.
  • The pressure-quenched superconducting state persisted in the same crystal structure (I-43d) as observed under compression.

Conclusions:

  • The enhancement of superconductivity during decompression is attributed to pressure-induced structural transitions (R-3m to I-43d), phonon softening, and carrier concentration variations.
  • This study demonstrates a novel route to enhance superconductivity through controlled decompression.
  • The findings suggest the possibility of achieving enhanced superconducting performance at lower or ambient pressures.