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Highly Fluorescent Pyridinium Betaines for Light Harvesting
Jingjing Xu1, Bolong Zhang1, Marina Jansen1,2
1School of Chemistry, The University of Melbourne, Bio21 Institute, 30 Flemington Road, Parkville, Victoria, 3010, Australia.
Abstract:
We report the findings of our experimental and theoretical investigations into the properties of pyridinium enolates and their potential utility in light-harvesting applications, such as in luminescent solar concentrators (LSCs). We present the synthesis, structures, photophysical characterization, and wavefunction-based quantum-chemical studies of five cyclobetaines. The performance of an LSC device incorporating one of these cyclobetaines is shown to be comparable to state-of-the-art devices.
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