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Highly Conductive Polypropylene-Graphene Nonwoven Composite via Interface Engineering.

Qin Pan1,2, Eunkyoung Shim1,2, Behnam Pourdeyhimi1,2

  • 1The Nonwovens Institute, North Carolina State University , Raleigh, North Carolina 27606, United States.

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Summary

We developed a highly conductive polypropylene-graphene nonwoven composite by coating polypropylene fabrics with graphene oxide and reducing it. This material achieves the highest conductivity in PP systems and shows promise for electronic textiles.

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Polymer Science

Background:

  • Developing conductive polymer composites is crucial for advanced electronic applications.
  • Polypropylene (PP) nonwoven fabrics offer a versatile substrate but lack inherent conductivity.
  • Achieving uniform graphene coatings on hydrophobic surfaces presents a significant challenge.

Purpose of the Study:

  • To create a highly conductive polypropylene-graphene nonwoven composite.
  • To investigate the effect of surface tension on coating uniformity and material properties.
  • To demonstrate the potential of the composite in energy storage devices.

Main Methods:

  • Direct coating of melt blown polypropylene nonwoven fabrics with graphene oxide (GO) dispersions in N,N-dimethylformamide (DMF).
  • Chemical reduction of GO to graphene using hydroiodic acid (HI).
  • Fabrication of a monolithic supercapacitor using direct laser patterning.

Main Results:

  • Achieved a conductivity of 35.6 S m-1 at 5.2 wt % graphene loading, the highest reported for conductive PP systems.
  • Demonstrated uniform GO coatings due to the matched surface tension between GO/DMF and the PP nonwoven.
  • Fabricated a sandwich supercapacitor with a high areal capacitance of 4.18 mF/cm2.

Conclusions:

  • The surface tension of coating baths significantly impacts coating uniformity and affinity.
  • The developed polypropylene-graphene nonwoven composite exhibits excellent conductivity and stability.
  • The composite shows great potential for applications in electronic textiles and energy storage devices.