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Updated: Feb 26, 2026

Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics
Published on: April 12, 2019
Insights into the electron-donating and withdrawing effect of the functional groups on mechanochemical
Fang Guo1, Zhen Wang1, Jin-Jing Zhang1
1College of Chemistry, Liaoning University, Shenyang 110036, China. fguo@lnu.edu.cn.
Abstract:
The effect of the withdrawing ability of -CF3 groups in a large and flexible bidentate ligand has been evaluated by monitoring the course of solid-state dehydrochlorination reactions. We demonstrate that the coordination bond formation does not occur by mechanochemical means from a second coordination sphere adduct. Quantum mechanical calculations have shown that frontier molecular orbital energy and net charges at N centers can justify the less reactive nature of the partially fluorinated ligand, corroborating the experimental results.
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