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Published on: April 18, 2019
Doping-induced carrier profiles in organic semiconductors determined from capacitive extraction-current transients
Mathias Nyman1, Oskar J Sandberg2, Staffan Dahlström2
1Physics/Faculty of Science and Engineering, and Center for Functional Materials, Åbo Akademi University, Porthansgatan 3, 20500, Turku, Finland. mathnyma@abo.fi.
Abstract:
A method to determine the doping induced charge carrier profiles in lightly and moderately doped organic semiconductor thin films is presented. The theory of the method of Charge Extraction by a Linearly Increasing Voltage technique in the doping-induced capacitive regime (doping-CELIV) is extended to the case with non-uniform doping profiles and the analytical description is verified with drift-diffusion simulations. The method is demonstrated experimentally on evaporated organic small-molecule thin films with a controlled doping profile, and solution-processed thin films where the non-uniform doping profile is unintentional, probably induced during the deposition process, and a priori unknown. Furthermore, the method offers a possibility of directly probing charge-density distributions at interfaces between highly doped and lightly doped or undoped layers.
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