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Qualitative Identification of Carboxylic Acids, Boronic Acids, and Amines Using Cruciform Fluorophores
Published on: August 19, 2013
Colorimetric and fluorescent detection of hydrazine with high sensitivity and excellent selectivity
Bingjie Shi1, Sujie Qi2, Mingming Yu2
1School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, Jiangsu Province, China; College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China.
Abstract:
It is critical to develop probes for rapid, selective, and sensitive detection of the highly toxic hydrazine in both environmental and biological science. In this work, under mild condition, a novel colorimetric and off-on fluorescent probe was synthesized for rapid recognition of hydrazine with excellent selectivity over other various species including some biological species, metal ions and anions. The limit of quantification (LOQ) value was 1.5×10-4M-3.2×10-3M (colorimetric method) and 1.5×10-4M-3.2×10-3M (fluorescent method) with as low as detection limit of 46.2μM.
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