Rheological characterisation of gluten from triticale (x Triticosecale Wittmack)

Triticale gluten still remains very poorly characterised rheologically. In this study the mechanical spectra of gluten isolated from four triticale cultivars were registered and fitted with Cole-Cole functions yielding the visco-elastic plateau parameters. Master spectra were calculated. A retardation test was performed and used to calculate the composite mechanical spectra and the width of visco-elastic plateau l. Protein fractional composition of triticale flour and gluten was studied using capillary zone electrophoresis.

Differentiated HMW-GS/SS compositions were identified in the triticale cultivars studied. The rheological parameters reached the following values: J_N⁰ 1.05·10^-3 to 2.69·10^-3 Pa^-1 , G_N⁰ 372 to 956 Pa, ω₀ 0.003 to 0.06 rad s^-1 , l 169 to 3121, J_e⁰ 1.57·10^-3 to 5.03·10^-3 Pa^-1 , G_e⁰ 199 to 637 Pa and η₀ 1.06·10⁷ to 3.93·10⁷ Pa s.

Visco-elastic properties of triticale gluten correspond to the lower end of medium visco-elasticity shown by common wheat gluten. Master spectra and the composite mechanical spectra prove that four triticale glutens exhibit practically an identical type of visco-elastic behaviour of a biopolymeric visco-elastic liquid similar to wheat gluten. The visco-elastic plateau parameters G_N⁰ , J_N⁰ , ω₀ and l appeared significantly correlated with the contents of prolamins and secaloglutenins in triticale flours and glutens. © 2017 Society of Chemical Industry.