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Spring-like motion caused large anisotropic thermal expansion in nonporous M(eim)2 (M = Zn, Cd)
Zhanning Liu1, Chenxi Liu, Qiang Li
1Department of Physical Chemistry, University of Science and Technology Beijing, Beijing, 100083, China. Xing@ustb.edu.cn.
Abstract:
Two nonporous coordination polymers were found to possess large anisotropic thermal expansion, which was derived from the flexible structures. A "spring-like" thermal motion was proposed to illustrate the mechanism. Compound Cd(eim)2 (eim = 2-ethylimidazole) possesses large linear and reversible thermal expansion properties and the emission intensity shows a linear decrease with temperature, making it a candidate for thermo-responsive materials.
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