Sonochemical synthesis of hydrogenated amorphous silicon nanoparticles from liquid trisilane at ambient temperature...

Silicon nanoparticles (Si-NPs) are increasing in relevance in diverse fields of scientific and nanotechnological inquiry, where currently some of the most important areas of research involve energy storage and biomedical applications. The present article is concerned with a curious and scalable method for the preparation of discrete, unoxidized, hydrogenated, and amorphous Si-NPs of tunable size in the range of 1.5-50nm. Using ultrasound generated with a conventional ultrasonic horn, the "fusion" of Si-NPs is demonstrated at ambient temperature and pressure by sonicating solutions containing readily available, semiconductor-grade purity trisilane (Si₃H₈). The only requirement for the synthesis is that it be carried out in an inert atmosphere such as that of a N₂-filled glove box. Various spectroscopic techniques and electron microscopy images are used to show that the size of the Si-NPs can be controlled by varying the amplitude of the ultrasonic waves or the concentration of trisilane in the solution. Moreover, sustained ultrasonic irradiation is found to yield highly porous Si-NP agglomerates that may find use in applications requiring non-crystalline nanoscopic high specific surface area morphologies.