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Coherent Random Lasing from Dye Aggregates in Polydimethylsiloxane Thin Films.

Lihua Ye1, Yangyang Feng1, Zhixiang Cheng1

  • 1Advanced Photonics Center, School of Electronic Science and Engineering, Southeast University , Nanjing 210018, P. R. China.

ACS Applied Materials & Interfaces
|July 25, 2017
PubMed
Summary

Researchers developed a low-threshold coherent random laser using dye-doped PDMS. Adding nanoparticles significantly reduced the pump threshold, enabling potential applications in optoelectronics and imaging.

Keywords:
PDMS thin filmleaky-waveguidemicro-/nanocrystalsmultiple scatteringrandom laser

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Area of Science:

  • Optics and Photonics
  • Materials Science

Background:

  • Coherent random lasers (CRLs) offer potential for advanced optical applications.
  • Optimizing pump thresholds and understanding feedback mechanisms are crucial for CRL development.

Purpose of the Study:

  • Investigate coherent random lasers (CRLs) in dye-doped polydimethylsiloxane (PDMS) thin films.
  • Explore the impact of nanoparticle doping and film structure on CRL performance.
  • Analyze the underlying mechanisms for feedback and wavelength tuning.

Main Methods:

  • Fabrication of pure dye and nanoparticle-doped (SiO2 NPs) thin films using PDMS and Pyrromethene 597 (PM597) dye.
  • Characterization of pump thresholds for coherent random lasing.
  • Analysis of the influence of film structure (e.g., substrate adhesion) on lasing properties.
  • Investigation of wavelength shifts by altering pump stripe length and film thickness.

Main Results:

  • Achieved a low pump threshold of 1.5 mJ/cm² in pure PM597 dye-doped PDMS films.
  • Reduced the pump threshold to 0.75 mJ/cm² with SiO2 nanoparticle doping.
  • Observed an increase in threshold upon film removal from the substrate, highlighting the role of leaky-waveguide structures.
  • Demonstrated red-shifts in peak wavelength (6.7 nm and 5.93 nm) by adjusting pump stripe length and film thickness, respectively.
  • Identified spontaneous formation of PM597 micro-/nanocrystals due to dye solubility changes and PDMS curing as the source of gain and feedback.

Conclusions:

  • Spontaneously formed dye micro-/nanocrystals in PDMS act as gain and feedback centers for CRLs.
  • Leaky-waveguide structures significantly contribute to lowering the CRL pump threshold.
  • The developed thin-film random laser is suitable for integrated optoelectronics and display imaging applications.