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Innovative Fly Ash Geopolymer-Epoxy Composites: Preparation, Microstructure and Mechanical Properties
Giuseppina Roviello1, Laura Ricciotti2, Oreste Tarallo3
1INSTM Research Group Napoli Parthenope, Centro Direzionale Napoli, Dipartimento di Ingegneria, Università di Napoli 'Parthenope', Isola C4, Napoli 80143, Italy. giuseppina.roviello@uniparthenope.it.
This study introduces novel composite materials using fly ash geopolymers and epoxy resins. These low-cost, high-performance binders offer improved mechanical properties for sustainable building applications.
Area of Science:
- Materials Science
- Civil Engineering
- Polymer Chemistry
Background:
- Geopolymers are inorganic binders with potential for sustainable construction.
- Fly ash is an industrial byproduct often requiring disposal.
- Epoxy resins offer tunable mechanical properties and adhesion.
Purpose of the Study:
- To develop and characterize novel composite materials from fly ash-based geopolymers and epoxy resins.
- To investigate the compatibility and mechanical performance of these new composites.
- To explore their potential as low-cost, sustainable building materials.
Main Methods:
- A synthetic method involving concurrent reticulation of organic (epoxy) and inorganic (geopolymer) components.
- Formation of hydrogen bonding between geopolymer and epoxy phases.
- Characterization of mechanical properties and comparison with neat geopolymers and metakaolin-based composites.
Main Results:
- High compatibility between fly ash geopolymer and epoxy resin phases due to hydrogen bonding.
- Significantly improved mechanical properties compared to neat geopolymers.
- Comparable performance to composites made with more expensive raw materials like metakaolin.
Conclusions:
- Novel, low-cost aluminosilicate binders were successfully produced using industrial byproducts.
- The composites exhibit excellent thixotropicity and adhesion for building applications.
- These materials represent a promising advancement in sustainable building technology.
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