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Updated: Feb 24, 2026

A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes

A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes

Published on: February 27, 2017

Click Chemistry in Functional Aliphatic Polycarbonates.

Yu Dai¹, Xiaojin Zhang¹, Fan Xia^1,2

¹Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan, 430074, P. R. China.

Macromolecular Rapid Communications

|August 11, 2017

Summary

This review highlights click chemistry

Keywords:

CO2-epoxy addition polymerization click chemistry modification ring-opening polymerization polycarbonates post-polymerization

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Design, Synthesis, and Photochemical Properties of Clickable Caged Compounds

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Design, Synthesis, and Photochemical Properties of Clickable Caged Compounds

Design, Synthesis, and Photochemical Properties of Clickable Caged Compounds

Published on: October 15, 2019

Area of Science:

Polymer Chemistry
Organic Synthesis

Background:

Functional aliphatic polycarbonates are biodegradable polymers with carbonate bonds.
Click chemistry is a vital conjugation method for synthesizing these polymers.

Purpose of the Study:

To review and highlight the applications of click chemistry in functional aliphatic polycarbonates.
To provide insights into designing polycarbonates for post-polymerization modification using click chemistry.

Main Methods:

Review of six categories of click reactions: alkyne-azide, thiol-ene, Michael addition, epoxy-amine/thiol, Diels-Alder, and imine formation.
Analysis of over 75 articles on click chemistry in functional aliphatic polycarbonates.

Main Results:

Click chemistry enables diverse post-polymerization modifications of polycarbonates.
Six key click reaction types are effective for modifying polycarbonates.

Conclusions:

Click chemistry is crucial for advancing functional aliphatic polycarbonates.
Understanding these reactions aids in designing polycarbonates for practical applications.