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Interface-Engineered Ni(OH)2 /β-like FeOOH Electrocatalysts for Highly Efficient and Stable Oxygen Evolution

Kaijian Zhu1, Wenjun Luo1, Guoxiang Zhu2

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This study introduces an efficient and stable nickel hydroxide/iron oxyhydroxide electrocatalyst for the oxygen evolution reaction (OER). Electroactivation enhances performance, offering a low-cost alternative to expensive catalysts.

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Area of Science:

  • Electrochemistry
  • Materials Science
  • Catalysis

Background:

  • Iron-based (oxy)hydroxides are promising electrocatalysts for the oxygen evolution reaction (OER) due to their abundance and low cost.
  • However, their practical application is limited by poor OER kinetics on the catalyst surface.

Purpose of the Study:

  • To develop a highly efficient and stable electrocatalyst for the OER using iron oxyhydroxide.
  • To investigate the role of electroactivation in enhancing the performance of bilayer electrocatalysts.

Main Methods:

  • Facile electroactivation treatment of a nickel hydroxide/β-like iron oxyhydroxide (Ni(OH)2/β-like FeOOH) composite.
  • Electrochemical characterization of the electrocatalyst's performance for OER.

Main Results:

  • The activated Ni(OH)2/β-like FeOOH exhibited an overpotential of 300 mV at 10 mA cm⁻² for OER.
  • The electrocatalyst demonstrated excellent stability with no current decay after 50 hours of testing.
  • Performance was comparable to state-of-the-art nickel- and cobalt-based electrocatalysts.

Conclusions:

  • The metastable tunnel structure of β-like FeOOH facilitates Ni²⁺ ion diffusion, enhancing OER performance during electroactivation.
  • This work presents a novel strategy for developing efficient, low-cost electrocatalysts and advances understanding of bilayer electrocatalyst mechanisms for OER.