Light-Driven Wettability Tailoring of Azopolymer Surfaces with Reconfigured Three-Dimensional Posts

The directional light-induced mass migration phenomenon arising in the photoresponsive azobenzene-containing materials has become an increasingly used approach for the fabrication of controlled tridimensional superficial textures. In the present work we demonstrate the tailoring of the superficial wettability of an azopolymer by means of the light-driven reconfiguration of an array of imprinted micropillars. Few simple illumination parameters are controlled to induce nontrivial wetting effects. Wetting anisotropy with controlled directionality, unidirectional spreading, and even polarization-intensity driven two-dimensional paths for wetting anisotropy are obtained starting from a single pristine pillar geometry. The obtained results prove that the versatility of the light-reconfiguration process, together with the possibility of reversible reshaping at reduced costs, represents a valid approach for both applications and fundamental studies in the field of geometry-based wettability of solid surfaces.