Construction of a superior visible-light-driven photocatalyst based on a C3N4 active centre-photoelectron shift
Sijing He1, Qinfeng Rong, Hongyun Niu
1State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. caiyaqi@rcees.ac.cn.
Abstract:
Herein, three functional factors inducing photocatalytic ability were artfully integrated into a covalent organic framework (COF), where triazine units served as photoactive centers, cyclic ketone units served as electron-withdrawing moieties, and the conjugated structure served as a photoelectron shift platform. This COF with segregated donor-acceptor alignments exhibits an excellent visible-light photocatalytic capacity for the decomposition of organic pollutants.
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