High-efficiency removal of lead from wastewater by biochar derived from anaerobic digestion sludge

The properties of biochar derived from waste activated sludge and anaerobic digestion sludge under pyrolysis temperature varying from 400°C to 800°C were investigated. The heavy metals adsorption efficiency of the sludge-derived biochar was also examined. Among the biochar samples tested, ADSBC600 possessing highly porous structure, special surface chemical behaviors and high thermal stability was found to remove Pb²⁺ from aqueous solutions efficiently with an adsorption capacity of 51.20mg/g. The Pb²⁺ adsorption kinetics and isotherm for ADSBC600 can be described using the pseudo second-order model and Langmuir isotherm, respectively. Analysis of the characteristics of biochar before and after metal treatment suggests that electrostatic attraction, precipitation, surface complexation and ion exchange are the possible Pb²⁺ removal mechanisms. This study demonstrates a successful example of waste refinery by converting anaerobic digestion sludge to feasible heavy metal adsorbents to implement the concept of circular economy.