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Unprecedented solvent induced inter-conversion between monomeric and dimeric silylene-zinc iodide adducts

Sandeep Yadav1, Ekta Sangtani, Diksha Dhawan

  • 1Inorganic Chemistry and Catalysis Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune 411008, India. ss.sen@ncl.res.in.

Dalton Transactions (Cambridge, England : 2003)
|August 17, 2017
PubMed
Summary

This study reveals a novel silylene-transition metal Lewis acid reaction, yielding both monomeric and dimeric adducts. Solvent choice dictates adduct formation and allows for spontaneous inter-conversion between forms.

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