High Order in a Self-Assembled Iridium(III) Complex Gelator Towards Nanostructured IrO₂ Thin Films

The preparation and characterization of a new metallogelator based on the Ir^III discrete cyclometalated complex [(ppy)₂ Ir(bpy)](CH₃ CH₂ OCH₂ CO₂ ) are reported, where H(ppy) is 2-phenylpiridine and bpy is 2,2'-bipyridine, which is used as an ancillary ligand. The compound is able to self-assemble in water in a range of concentrations between 3 % and 6 % w/w, creating a luminescent ordered supramolecular gel. The gel and xerogel architectures were investigated through polarized optical microscopy (POM), SEM and TEM microscopies coupled with powder X-ray diffraction. The gel supramolecular organization is characterized by columnar tetragonal strands, already present at high dilution conditions, of cations surrounded by counteranions. These strands, in turn, are self-assembled in an oblique columnar cell upon gelification. The xerogel thin films obtained upon complete dehydration maintained the gel supramolecular order and can be used as a precursor for the preparation of nanostructured IrO₂ thin films.