Utilization of waste bittern from saltern as a source for magnesium and an absorbent for carbon dioxide capture

During solar salt production, large quantities of bittern, a liquid by-product containing high inorganic substance concentrations, are produced. The purpose of this research was to examine the utilization of waste bittern generated from salterns as a source for Mg production and as an absorbent for carbon dioxide (CO₂) capture. The study was conducted in a sequential two-step process. At NaOH/Mg molar ratios of 2.70-2.75 and pH 9.5-10.0, > 99% Mg precipitation from the bittern was achieved. After washing with water, 100-120 g/L of precipitate containing 94% Mg(OH)₂ was recovered from the bittern. At the optimum NH₄OH concentration of 5%, 120 g of sodium bicarbonate precipitate per liter of bittern were recovered, which was equivalent to 63 g CO₂ captured per liter of bittern. These results can be used to support the use of bittern as a resource and reduce economic losses during solar salt production.