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Updated: Feb 24, 2026
Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten
Darya V Evtushok1, Anatoly R Melnikov, Natalya A Vorotnikova
1Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation. shtopy@niic.nsc.ru.
Abstract:
Octahedral metal cluster complexes have high potential for biomedical applications. In order to evaluate the benefits of these moieties for combined CT/X-ray luminescence computed tomography, this paper compares photoluminescence, radiodensity and X-ray induced luminescence properties of eight related octahedral molybdenum and tungsten cluster complexes [{M6I8}L6]n (where M is Mo or W and L is I-, NO3-, OTs- or OH-/H2O). This article demonstrates that despite the fact that molybdenum cluster complexes are better photoluminescence emitters, tungsten cluster complexes, in particular (Bu4N)2[{W6I8}I6], demonstrate significantly higher X-ray induced luminescence due to a combination of relatively good photoluminescence properties and high X-ray attenuation. Additionally, photo-degradation of [{M6I8}(NO3)6]2- was evaluated.
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