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Similarity Laws for the Lines of Ideal Free Energy and Chemical Potential in Supercritical Fluids
E M Apfelbaum1, V S Vorob'ev1,2
1Joint Institute for High Temperatures of Russian Academy of Sciences , Izhorskaya Street 13 Bldg. 2, Moscow 125412, Russia.
Abstract:
We have found the curves on the density-temperature plane, along which the values of free energy and chemical potential correspond to ideal gas quantities. At first, we have applied the van der Waals equation to construct them and to derive their equations. Then we have shown that the same lines for real substances (Ar, N2, CH4, SF6, H2, H2O) and for the model Lennard-Jones system constructed on the basis of the measurements data and calculations are well matched with the derived equations. The validity and deviations from the obtained similarity laws are discussed.
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