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A highly luminescent entangled metal-organic framework based on pyridine-substituted tetraphenylethene for efficient
Chen-Lei Tao1, Bin Chen, Xun-Gao Liu
1College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 310036, China. xungaoliu@hznu.edu.cn.
Abstract:
A novel pillared-layered entangled luminescent metal-organic framework [Zn2(bpdc)2(BPyTPE)] (1) (BPyTPE = (E)-1,2-diphenyl-1,2-bis(4-(pyridin-4-yl)phenyl)ethene) has been designed and constructed. The solvent-free 1 exhibits strong blue-green emission with an excellent fluorescence quantum yield of 99% and provides a facile and reversible method to sensitively and quantitatively detect trace pesticide of 2,6-dichloro-4-nitroaniline.
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