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Sensitive Photoacoustic IR Spectroscopy for the Characterization of Amino/Azido Mixed-Linker Metal-Organic Frameworks

Jerome Canivet1, Vladimir Lysenko2, Jaakko Lehtinen3

  • 1Univ. Lyon, Université Claude Bernard Lyon 1, CNRS, IRCELYON-UMR 5256, 2 Av. Albert Einstein, 69626, Villeurbanne, France.

Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
|August 24, 2017
PubMed

Keywords:
azidesinfrared spectroscopymaterials sciencemetal-organic frameworksphotoacoustics

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Infrared spectroscopy, also known as vibrational spectroscopy, is mainly used to determine the types of bonds and functional groups in molecules. In aldehydes and ketones, the carbonyl (C=O) bond shows an absorption around 1710 cm-1. The C=O bond vibration of an aldehyde occurs at lower frequencies than that of a ketone. In addition to the C=O absorption in an aldehyde, the aldehydic C–H bond also gives two peaks in the 2700–2800 cm-1 range. This absorption, coupled with the C=O stretching, is...