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Related Experiment Video

Updated: Feb 24, 2026

Microfluidic Fabrication Techniques for High-Pressure Testing of Microscale Supercritical CO2 Foam Transport in Fractured Unconventional Reservoirs
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Pressure-Responsive, Surfactant-Free CO2-Based Nanostructured Fluids.

Natascia Grimaldi, Paula Elena Rojas1, Simon Stehle2,3

  • 1Centro de Investigacion Biomedica en Red de Bioingenieria, Biomateriales y Nanomedicina (CIBER-BBN) , 28029 Madrid, Spain.

ACS Nano
|August 29, 2017
PubMed
Summary

Researchers developed novel surfactant-free, carbon dioxide (CO2)-based microemulsions. These systems exhibit pressure-responsive nanostructuration for tunable mixing and demixing, offering sustainable chemical processing solutions.

Keywords:
MD simulationsRamanSANScompressed CO2microemulsionnanostructured fluidsneutron scatteringsurfactant-free

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Area of Science:

  • Physical Chemistry
  • Materials Science
  • Chemical Engineering

Background:

  • Traditional microemulsions require significant surfactant amounts, posing economic and environmental challenges.
  • Surfactants in microemulsions can act as contaminants in advanced material and chemical processing.
  • Developing surfactant-free alternatives is crucial for sustainable industrial applications.

Purpose of the Study:

  • To investigate the nanostructuration of novel surfactant-free, carbon dioxide (CO2)-based microemulsion-like systems.
  • To characterize the pressure-responsive behavior of these CO2-based fluids.
  • To explore their potential applications in molecular material processing and chemical engineering.

Main Methods:

  • Raman spectroscopy
  • Molecular dynamics simulations
  • Small-angle neutron scattering

Main Results:

  • Observation and characterization of "water-rich" nanodomains within a "water-depleted" matrix.
  • Demonstration of reversible, pressure-triggered nanostructuration and spontaneous formation.
  • Confirmation of rapid, homogeneous mixing/demixing upon pressure changes.

Conclusions:

  • Surfactant-free CO2-based microemulsion-like systems exhibit unique pressure-responsive nanostructuration.
  • These fluids offer spontaneous formation, tunable solvation, and contaminant-free processing.
  • Their properties make them highly appealing for advanced molecular material processing and chemical engineering.