Synthesis of cobalt-impregnated carbon composite derived from a renewable resource: Characterization and catalytic...

A novel nitrogen-doped biochar embedded with cobalt (Co-NB) was fabricated via pyrolysis of glucose pretreated with melamine (N donor) and Co(II). The Co-NB showed high catalytic capability by converting p-nitrophenol (PNP) into p-aminophenol (PAP) by NaBH₄. The analyses of FE-SEM, TEM, BET, XRD, Raman, and X-ray photoelectron spectroscopy XPS of the Co-NB showed hierarchical porous structure (BET 326.5m²g^-1 and pore volume: 0.2403cm³g^-1) with well-dispersed Co nanoparticles (20-60nm) on the N-doped graphitic biochar surface. The Co-NB showed higher PNP reduction capability compared to the Co-biochar without N-doping, achieving 94.3% removal within 4min at 0.24gL^-1 catalyst dose and initial concentration of 0.35mM PNP. Further conversion experiments under varying environmental conditions (e.g., NaBH₄ concentration (7.5-30mM), biochar dosage (0.12-1.0gL^-1), initial PNP concentration (0.08-0.17mM)) were conducted in batch mode. The reusability of Co-NB was validated by the repetitive conversion experiments (5cycles). The overall results demonstrated biochar potential as catalysts for environmental applications if properly designed.