Few-Layered Trigonal WS₂ Nanosheet-Coated Graphite Foam as an Efficient Free-Standing Electrode for a Hydrogen...

Few-layered tungsten disulfide (WS₂) with a controlled-phase ratio (the highest trigonal-phase ratio being 67%) was exfoliated via lithium insertion. The exfoliated WS₂ nanosheets were then anchored onto three-dimensional (3D) graphite foam (GF) to fabricate free-standing binder-free electrodes. The 3D GF can increase the interfacial contact between the WS₂ nanosheets and the electrolyte and facilitate ion transfer. Without the nonconductive binder, an intimate contact between the WS₂ and GF interface can be created, leading to the improvement of electrical conductivity. In comparison to the pure WS₂ nanosheets, the overpotential for a hydrogen evolution reaction is significantly decreased from 350 mV to 190 mV at 10 mA/cm², and no deactivation occurs after 1000 cycles. The density functional theory computations reveal that the efficient catalytic activity of the trigonal-phase WS₂/GF electrode is attributed to the lower Gibbs free energy for H* adsorption and higher electrical conductivity.