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Updated: Feb 23, 2026

Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
Published on: July 14, 2015
New stationary phases for gas chromatography based on polymers with intrinsic porosity
E Yakubenko1, A Korolev1, P Chapala1
1Topchiev Institute of Petrochemical Synthesis RAS, 119991, Moscow, Lenin av. 29, Russia.
Abstract:
Norbornene polymers with intrinsic porosity were investigated as candidates for polymeric stationary phases in capillary GC. Kinetic and thermodynamic characteristics of the stationary phases were evaluated and turned out that only polymer with vicinal distribution of trimethylsilyl groups (polymer II) provided properties making it potential candidate for application in capillary GC. Columns with stationary phase based on polymer II demonstrated unique selectivity, moderate thermostability and efficiency better than previously studied columns with stationary phase based on poly[(1-trimethylsilyl)-1-propine].
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