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Related Concept Videos

Types of Step-Growth Polymers: Polyesters01:20

Types of Step-Growth Polymers: Polyesters

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The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the polymer...
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Step-Growth Polymerization: Overview01:03

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Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
Many natural and synthetic polymers are produced by...
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Olefin Metathesis Polymerization: Overview01:13

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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
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The conversion of alkenes to macromolecules called polymers is a reaction of high commercial importance. The structure of the polymer is defined by a repeating unit, while the terminal groups are considered insignificant. The average degree of polymerization represents the number of repeating units in the polymer molecule and is denoted by the subscript n.
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Anionic Chain-Growth Polymerization: Overview01:20

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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
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Polymers02:34

Polymers

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The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
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Designed for Molecular Recycling: A Lignin-Derived Semi-aromatic Biobased Polymer
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[Advances in platform compounds and polymers from vegetable oils].

Xin He1, Guiying Wu1, Yunjun Yan1

  • 1College of Life Science and Technology, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China.

Sheng Wu Gong Cheng Xue Bao = Chinese Journal of Biotechnology
|September 7, 2017
PubMed
Summary

Vegetable oils offer a sustainable alternative to petroleum, yielding valuable platform compounds and polymers. This review details their development, properties, and future research directions in biochemical engineering.

Keywords:
glycerolplatform compoundpolymervegetable oil

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Area of Science:

  • Biochemical Engineering
  • Polymer Science
  • Sustainable Chemistry

Background:

  • Vegetable oils are increasingly recognized as a viable, renewable alternative to petroleum-based resources.
  • The chemical modification of vegetable oils is crucial for developing sustainable materials.
  • Platform compounds derived from vegetable oils are key intermediates for various applications.

Purpose of the Study:

  • To review the influence of vegetable oil structure on platform compounds and polymers.
  • To systematically introduce the latest developments and progress in oil-based platform compounds and polymers.
  • To summarize challenges and future directions in this research area.

Main Methods:

  • Literature review of scientific publications on vegetable oil utilization.
  • Analysis of structure-property relationships for oil-derived compounds and polymers.
  • Synthesis of information on current research trends and challenges.

Main Results:

  • Vegetable oil structure significantly impacts the properties of derived platform compounds and polymers.
  • Recent advancements show promising developments in the synthesis and application of these materials.
  • Key challenges include scalability, cost-effectiveness, and performance optimization.

Conclusions:

  • Vegetable oil-derived platform compounds and polymers represent a significant advancement in sustainable chemistry.
  • Further research is needed to overcome existing challenges and fully realize their potential.
  • This field offers substantial prospects for biochemical engineering and materials science.