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Updated: Feb 23, 2026

Sampling and Pretreatment of Tooth Enamel Carbonate for Stable Carbon and Oxygen Isotope Analysis
Published on: August 15, 2018
Direct, Precise Measurements of Isotopologue Abundance Ratios in CO2 Using Molecular Absorption Spectroscopy:
Tim Stoltmann1,2,3, Mathieu Casado3, Mathieu Daëron3
1CNRS, LIPhy , F-38000 Grenoble, France.
Abstract:
We present an ultrasensitive absorption spectrometer based on a 30 Hz/s stability, sub-kHz line width laser source coupled to a high-stability cavity-ring-down-spectroscopy setup. It provides direct and precise measurements of the isotopic ratios δ17O and δ18O in CO2. We demonstrate the first optical absorption measurements of 17O anomalies in CO2 with a precision better than 10 ppm, matching the requirements for paleo-environmental applications. This illustrates how optical absorption methods have become a competitive alternative to state-of-the-art isotopic ratio mass spectrometry techniques.
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