Synthesis and characterization of an iron-impregnated biochar for aqueous arsenic removal

The iron (Fe)-impregnated biochar (FBC), fabricated via thermal pyrolysis of corn straw treated with FeCl₃, was investigated for the sorption characteristics and mechanisms of aqueous arsenate removal. Structural and morphological analysis showed that large quantity of iron oxide particles tightly grew within the porous matrix of biochar (BC) through iron-impregnation. Batch sorption experimental results showed that the composite, with larger surface area, more functional groups, and greater thermal stability, exhibited excellent As(V) adsorption efficiency of 6.80mg/g compared to 0.017mg/g for unmodified BC (a 400-fold increase). The adsorption kinetics data were fitted well by pseudo second-order model, and sorption isotherms of As(V) were simulated well by both Freundlich and Langmuir models. XRD and FTIR analysis suggested that electrostatic attraction and precipitation were dominant mechanisms for As(V) sorption. The As(V)-loaded FBC could be easily separated from the solution by a magnet at the end of the sorption experiment. The FBC showed excellent re-sorption capacity, which account for about 70% removal efficiency for the second and third reuse in As(V) sorption. Results from this study demonstrated the promise of FBC composite as an efficient, low-cost, environmentally friendly, and regenerable adsorbent for As(V) remediation.

FBC showed enhanced As(V) sorption capacity, excellent re-sorption capacity, and could be easily separated by a magnet.