Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

1.8K
Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.
1.8K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Identification of a mechanism-based binding mode for a histone deacetylase 6 inhibitor.

Nature communications·2026
Same author

Prognostic Factors for Adulthood Psychosis in Adolescent Psychiatry Services: A Longitudinal Total Birth Cohort Study.

Schizophrenia bulletin·2026
Same author

Adolescent polysubstance use and psychopathology: a population-based survey in schools.

Irish journal of psychological medicine·2026
Same author

Positive childhood experiences and associations with plasma inflammatory markers in early adulthood.

Brain, behavior, and immunity·2026
Same author

Childhood immunomodulatory biomarkers and risk of depression and psychosis-spectrum outcomes at age 24: longitudinal evidence from the ALSPAC birth cohort.

Brain, behavior, and immunity·2026
Same author

Doxycycline and Schizophrenia: Response to Letters.

The American journal of psychiatry·2026

Related Experiment Video

Updated: Feb 23, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
06:40

Synthesis of a Water-soluble Metal–Organic Complex Array

Published on: October 8, 2016

12.0K

Hetero-metallic, functionalizable polyoxomolybdate clusters via a "top-down" synthetic method.

Colm Healy1, Brendan Twamley, Munuswamy Venkatesan

  • 1School of Chemistry & CRANN Institute, University of Dublin, Trinity College, Dublin 2, Ireland. schmittw@tcd.ie.

Chemical Communications (Cambridge, England)
|September 15, 2017
PubMed
Summary

Researchers synthesized novel bi-metallic polyoxomolybdate clusters by disassembling and reassembling molybdenum and copper species. This method creates complex organophosphonate-stabilized structures with potential applications in materials science.

More Related Videos

High Resolution Physical Characterization of Single Metallic Nanoparticles
09:56

High Resolution Physical Characterization of Single Metallic Nanoparticles

Published on: June 28, 2019

6.2K
Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

16.6K

Related Experiment Videos

Last Updated: Feb 23, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
06:40

Synthesis of a Water-soluble Metal–Organic Complex Array

Published on: October 8, 2016

12.0K
High Resolution Physical Characterization of Single Metallic Nanoparticles
09:56

High Resolution Physical Characterization of Single Metallic Nanoparticles

Published on: June 28, 2019

6.2K
Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

16.6K

Area of Science:

  • Inorganic Chemistry
  • Materials Science
  • Supramolecular Chemistry

Background:

  • Polyoxometalates (POMs) are versatile inorganic clusters with tunable properties.
  • Bi-metallic POMs offer unique structural and electronic characteristics.
  • Organophosphonate ligands can stabilize and functionalize POM structures.

Purpose of the Study:

  • To synthesize and characterize novel bi-metallic, organophosphonate-stabilized polyoxomolybdate clusters.
  • To investigate the assembly mechanism involving disassembly and reassembly of precursor species.
  • To explore the structural diversity achievable through controlled decomposition and reconstruction.

Main Methods:

  • In situ disassembly of Lindqvist hexamolybdate ([Mo6O19]2-) species.
  • Reassembly with polynuclear Copper(II) assemblies.
  • Characterization of the resulting bi-metallic clusters using analytical techniques.

Main Results:

  • Successful synthesis of two distinct bi-metallic clusters: [Mo6Cu4O16(OH)2(C4H9PO3)4(C5H5N)2(CH3O)4(H2O)]2- and [Mo7Cu7O19(OH)(CH3O)7(C4H9PO3)6(C5H5N)2]2-.
  • Demonstration of a
  • top-down
  • approach for constructing complex POM architectures.
  • Identification of organophosphonate ligands role in stabilizing the sandwich-type structures.

Conclusions:

  • The study presents a novel synthetic route to complex bi-metallic polyoxomolybdate clusters.
  • The
  • top-down
  • disassembly-reassembly strategy is effective for generating intricate POM structures.
  • These findings expand the scope of POM chemistry and offer new avenues for materials design.