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A Fabrication Method for Highly Stretchable Conductors with Silver Nanowires
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The Joule heating problem in silver nanowire transparent electrodes.

H H Khaligh1,2, L Xu2,3, A Khosropour1,2

  • 1Department of Electrical & Computer Engineering, University of Waterloo, Waterloo, ON N2L 3G1, Canada.

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|September 21, 2017
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Summary

Silver nanowire electrodes cause dangerous hotspots, leading to failure. Graphene passivation helps but shifts failure to substrate melting, highlighting critical challenges for transparent conductive materials.

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Area of Science:

  • Materials Science
  • Electrical Engineering
  • Nanotechnology

Background:

  • Silver nanowire transparent electrodes offer an alternative to indium tin oxide (ITO).
  • Joule heating presents a significant challenge for silver nanowire electrode performance and longevity.

Purpose of the Study:

  • To investigate the unique Joule heating problem in silver nanowire transparent electrodes.
  • To analyze the impact of hotspots on electrode degradation and failure mechanisms.
  • To evaluate the effectiveness of graphene as a passivation layer.

Main Methods:

  • Surface temperature mapping to identify hotspots.
  • Lifetime testing under continuous current flow.
  • Post-mortem analysis and computational modeling.

Main Results:

  • Silver nanowire electrodes exhibit severe temperature non-uniformity, reaching over 250 °C at localized points, unlike ITO.
  • Hotspots accelerate nanowire degradation, causing electrode failure within 5 days.
  • Graphene passivation reduces nanowire degradation and improves temperature uniformity but shifts failure to substrate melting.

Conclusions:

  • Joule heating is a critical failure mechanism for silver nanowire transparent electrodes.
  • Graphene passivation mitigates but does not eliminate Joule heating issues.
  • Managing Joule heating is essential for the practical application of silver nanowire electrodes in devices like organic solar cells.