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Updated: Feb 22, 2026

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
Published on: October 24, 2017
Single-Molecule-based White-Light Emissive Organic Solids with Molecular-Packing-Dependent Thermally Activated
Yuewei Zhang1, Yang Miao1, Xiaoxian Song1
1State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University , Changchun 130012, P. R. China.
Abstract:
White-light-emitting single molecules have attracted broad attention because of their great potential for use in flat-panel displays and future light sources. We report a unique molecule of 3-(diphenylamino)-9H-xanthen-9-one (3-DPH-XO), which was found to exhibit bright white-light emission in the solid state caused by the spontaneous formation of a mixture with different polymorphs. Single-crystal analyses demonstrate that noncovalent interactions (such as π···π stacking, hydrogen bonding, and C-H···π interactions) induce different stacking arrangements (polymorphs A, B, and C) with different photophysical properties in a molecular solid. In addition, crystals B and C with the acceptor···acceptor stacking feature show the thermally activated delayed fluorescence (TADF) characteristics, indicating that appropriate noncovalent interactions could enhance the reverse intersystem crossing process and consequently lead to delayed fluorescence. This discovery provides an effective strategy for the design of new white-light-emitting single molecules as well as TADF materials.
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