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Updated: Feb 22, 2026

Synthesis and Functionalization of 3D Nano-graphene Materials: Graphene Aerogels and Graphene Macro Assemblies
Published on: November 5, 2015
Interface structure between tetraglyme and graphite
Taketoshi Minato1, Yuki Araki2, Kenichi Umeda3
1Office of Society-Academia Collaboration for Innovation, Kyoto University, Katsura, Nishikyo, Kyoto 615-8510, Japan.
Abstract:
Clarification of the details of the interface structure between liquids and solids is crucial for understanding the fundamental processes of physical functions. Herein, we investigate the structure of the interface between tetraglyme and graphite and propose a model for the interface structure based on the observation of frequency-modulation atomic force microscopy in liquids. The ordering and distorted adsorption of tetraglyme on graphite were observed. It is found that tetraglyme stably adsorbs on graphite. Density functional theory calculations supported the adsorption structure. In the liquid phase, there is a layered structure of the molecular distribution with an average distance of 0.60 nm between layers.
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