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Electrostatic Boundary Conditions in Dielectrics01:27

Electrostatic Boundary Conditions in Dielectrics

1.9K
When an electric field passes from one homogeneous medium to another, crossing the boundary between the two mediums imparts a discontinuity in the electric field. This results in electrostatic boundary conditions that depend on the type of mediums the field propagates through.
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's permittivity....
1.9K
Second Uniqueness Theorem01:16

Second Uniqueness Theorem

2.7K
Consider a region consisting of several individual conductors with a definite charge density in the region between these conductors. The second uniqueness theorem states that if the total charge on each conductor and the charge density in the in-between region are known, then the electric field can be uniquely determined.
In contrast, consider that the electric field is non-unique and apply Gauss's law in divergence form in the region between the conductors and the integral form to the surface...
2.7K
Potential Due to a Polarized Object01:29

Potential Due to a Polarized Object

827
A neutral atom consists of a positively charged nucleus surrounded by a negatively charged electron cloud. When placed in an external electric field, the external electric force pulls the electrons and nucleus apart, opposite to the intrinsic attraction between the nucleus and the electrons. The opposing forces balance each other with a slight shift between the center of masses of the nucleus and the electron cloud, resulting in a polarized atom. On the other hand, a few molecules, like water,...
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Electrostatic Boundary Conditions01:16

Electrostatic Boundary Conditions

1.0K
Consider an external electric field propagating through a homogeneous medium. When the electric field crosses the surface boundary of the medium, it undergoes a discontinuity. The electric field can be resolved into normal and tangential components. The amount by which the field changes at any boundary is given by the difference between the field components above and below the surface boundary.
The surface integral of an electric field is given by Gauss's law in integral form and is related to...
1.0K
Electric Field of Two Equal and Opposite Charges01:30

Electric Field of Two Equal and Opposite Charges

7.2K
Atoms generally contain the same number of positively and negatively charged particles, protons, and electrons. Hence, they are electrically neutral. However, the centers of the positive and negative charges do not always coincide. In such a scenario, the electric field of an atom may not be zero.
A separation of the positive and negative charges can lead to a weak, remnant effect of the positive and negative charges. The expectation is that the more the distance between the positive and...
7.2K
Boundary Conditions for Current Density01:25

Boundary Conditions for Current Density

1.4K
Current density becomes discontinuous across an interface of materials with different electrical conductivities. The normal component of the current density is continuous across the boundary.
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Related Experiment Video

Updated: Feb 22, 2026

Finite Element Modelling of a Cellular Electric Microenvironment
08:23

Finite Element Modelling of a Cellular Electric Microenvironment

Published on: May 18, 2021

4.0K

The electroneutrality constraint in nonlocal models.

Eitan Lees1, Srujan Rokkam2, Sachin Shanbhag1

  • 1Department of Scientific Computing, Florida State University, Tallahassee, Florida 32306, USA.

The Journal of Chemical Physics
|October 2, 2017
PubMed
Summary

We developed a nonlocal Nernst-Planck model for ionic systems. Gauss

Area of Science:

  • Computational chemistry
  • Physical chemistry
  • Chemical engineering

Background:

  • Multicomponent ionic systems involve complex reaction and diffusion dynamics.
  • Modeling ion transport across membranes requires accounting for induced electric fields.
  • Strict electroneutrality is a key criterion in ionic system simulations.

Purpose of the Study:

  • To develop and apply a nonlocal Nernst-Planck model for multicomponent ionic systems.
  • To investigate the performance of charge conservation and Gauss' law in modeling electric fields.
  • To assess the adherence to strict electroneutrality under various initial conditions.

Main Methods:

  • Development of a nonlocal Nernst-Planck model.
  • Application to a one-dimensional liquid junction problem with a permeable membrane.

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  • Modeling induced electric fields using nonlocal charge conservation and Gauss' law.
  • Analysis of four different initial scenarios to evaluate electroneutrality.
  • Main Results:

    • Both charge conservation and Gauss' law provide similar results when initial conditions satisfy strict electroneutrality.
    • Gauss' law demonstrates superior numerical stability, especially when species concentrations approach zero.
    • Gauss' law is computationally more efficient than charge conservation.
    • Insights into electroneutrality conditions for nonlocal peridynamic models were gained.

    Conclusions:

    • Gauss' law offers significant advantages in numerical stability and computational cost for modeling ionic systems.
    • The study provides crucial insights for handling evolving charges in nonlocal reaction-diffusion and corrosion models.
    • The developed model and findings are applicable to various electrochemical and materials science problems.