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Updated: Feb 22, 2026

Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
Published on: July 14, 2015
Hierarchically porous organic polymers: highly enhanced gas uptake and transport through templated synthesis
Sanjiban Chakraborty1, Yamil J Colón2, Randall Q Snurr2
1Department of Chemistry and the International Institute for Nanotechnology , Northwestern University , 2145 Sheridan Road , Evanston , Illinois 60208-3113 , USA .
Abstract:
Porous organic polymers (POPs) possessing meso- and micropores can be obtained by carrying out the polymerization inside a mesoporous silica aerogel template and then removing the template after polymerization. The total pore volume (tpv) and specific surface area (ssa) can be greatly enhanced by modifying the template (up to 210% increase for tpv and 73% for ssa) as well as by supercritical processing of the POPs (up to an additional 142% increase for tpv and an additional 32% for ssa) to include larger mesopores. The broad range of pores allows for faster transport of molecules through the hierarchically porous POPs, resulting in increased diffusion rates and faster gas uptake compared to POPs with only micropores.
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