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Updated: Feb 21, 2026
Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
Efficient Solar-Assisted O2 Reduction Using a Cofacial Iron Porphyrin Dimer Catalyst Integrated into a p-CuBi2 O4
Zaki N Zahran1,2, Eman A Mohamed1, Ashraf Abdel Haleem1,3
1Center for Chemical Energy Conversion Research, Institute for Science and Technology Research, Chubu University, Kasugai, 487-8501, Japan.
Abstract:
A cofacial iron porphyrin heterodimer, Fe2 TPFPP-TMP showed high electrocatalytic activity, selectivity, and stability for O2 reduction to H2 O both in homogeneous non-aqueous and heterogeneous neutral aqueous solutions. When it is integrated to FTO/p-CuBi2 O4 (FTO=fluorine doped tin oxide) photocathode prepared by a simple novel method, a remarkable efficient solar-assisted O2 reduction is achieved in neutral potassium phosphate (KPi) or basic NaOH solutions saturated with O2 .
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