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Updated: Feb 21, 2026
Molten-Salt Synthesis of Complex Metal Oxide Nanoparticles
Published on: October 27, 2018
A commensurately modulated structure of parabutlerite, FeIIISO4(OH)·2H2O
Jakub Plášil1, Václav Petříček1, Juraj Majzlan2
1Institute of Physics ASCR, v.v.i., Na Slovance 2, Praha 8, 18221, Czech Republic.
Abstract:
Parabutlerite, orthorhombic FeIIISO4(OH)·2H2O, has been reinvestigated using single-crystal X-ray diffraction. The structure of parabutlerite is commensurately modulated, with a = 20.0789 (8), b = 7.4024 (7), c = 7.2294 (15) Å and q = 0.4b*. The superstructure has been determined, using a superspace approach, as having the superspace group Pnma(0β0)s0s and t0 = 1/20, and refined to R = 0.0295 for 2392 main reflections with I > 3σ(I). The structure consists of infinite chains of Fe octahedra that are linked via vertices (OH groups); these chains are encased from both sides by SO4 tetrahedra. The displacive modulation of atoms in parabutlerite is connected with a tilt of the chains around the b axis towards the adjacent chains due to the accommodation of an energetically more favorable hydrogen-bond geometry.
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